Analysis of Polydimethylsiloxanes
Three polydimethylsiloxane compounds: octamethylcyclotetrasiloxane (sample 1), decamethylcyclopentasiloxane (sample 2) and octa(dimethylsiloxy)silsesquioxane (sample 3), were analyzed using a GC/TOFMS. The first two samples are relatively small molecules with molecular weights of 296 and 370, respectively, so they were introduced into the system through the mass reference sample inlet (reservoir). Sample 3 is a much bigger molecule with a molecular weight of 1,016 that could not be introduced through the reservoir. As a result, this sample was introduced by injecting it into the GC.
For this work, each sample was analyzed by using the JEOL AccuTOF-GC with both EI (hard ionization) and FI (soft ionization).