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Optically active covalent organic frameworks and hyperbranched polymers with chirality induced by circularly polarized light

Abstract

Axial chirality was induced by circularly polarized light to covalent organic frameworks as well as hyperbranched polymers composed of bezene-1,3,5-triyl core units and oligo(benzene-1,4-diyl) as linker units where variation in induction efficiency was rationally interpreted in terms of internal rotation dynamics studied through CPMAS 13C NMR experiments including CODEX measurements.

Click Link to View Article: https://doi.org/10.1039/D1CC02671B

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