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• PaperSpray® Accessory for AccuTOF™-LP and AccuTOF™-DART® Systems

  PaperSpray Principle: Samples and a polar solvent such as methanol are deposited onto a porous substrate such as filter paper or chromatography paper cut into a triangle. When a high voltage (typically ~3000V) is applied, Electrospray Ionization (ESI) occurs at the tip of the paper triangle. PaperSpray is simpler than ESI and does not require a pump, spray needle, desolvating gas or precise alignment.
• The AccuTOF™-DART® 4G: The Ambient Ionization Toolbox™

  JEOL introduced the AccuTOF-DART in 2005 as the first commercially available ambient ionization mass spectrometer system. The atmospheric pressure ionization interface (API) for the AccuTOF system, originally designed as a simple, rugged and reliable LC/MS interface, became the ideal platform for developing the Direct Analysis in Real Time (DART) ion source. Because the DART ion source can be positioned directly in front of the AccuTOF sampling orifice without additional interface hardware, a variety of ambient ionization techniques are available to the AccuTOF-DART operator without removing the DART ion source. The third-generation AccuTOF-DART 4G system is an “ambient ionization toolbox” that allows the analyst to choose ionization methods that are best matched to the samples to be analyzed.
• Metal-Templated Oligomeric Macrocyclization via Coupling for Metal-Doped π-Systems

  A method for the synthesis of metal-doped aromatic macrocycles has been developed. The method, i.e., metal-templated oligomeric macrocyclization via coupling, adopts Ni as the template and assembles five pyridine units via a Ni-mediated coupling reaction to form aryl–aryl linkages. A pentameric oligopyridyl macrocycle was selectively obtained in good yield, and the reaction was also applicable to a gram-scale synthesis. The pentameric oligopyridyl macrocycle captured d8-Ni(II) at the center to form a paramagnetic pentagonal-bipyramidal complex. The method was applied to the synthesis of a large π-molecule to afford a nanometer-sized, bowl-shaped molecule having a unique combination of 120π and 8d electrons.
• Lithium Ion Battery Note

  The applications for lithium ion batteries (LIB) cover a wide range, from power sources for personal computers and mobile devices to automobiles, and there is always a demand for even better performance and safety. In order to ensure the performance and quality of LIB, analysis and evaluation using high-performance assessment systems is necessary. JEOL offers a full line-up of equipment to support the development of new LIB technologies and to improve product quality, including instruments for morphology observation and surface analysis, chemical analysis systems to perform structural analysis on a molecular level, as well as fabrication systems to create high-performance coatings and powders. This LIB note offers solutions for researchers and engineers who are looking for the best equipment for their application.
• New Generation LC-TOF/MS “AccuTOFTM”

  It has been a decade since Dodonov and his colleagues [1] first announced the electrospray ionization time-of-flight mass spectrometer (ESI-TOF MS). Their initial findings have been enhanced by Standing and others [2,][ 3], and it has been recently reported that a large TOF MS system achieved a mass resolution exceeding 10,000 [4]. Encouraged by the results acquired by Dodonov and Standing, some of the MS manufactures have produced bench top ESI-TOF MS systems. However, most of these commercial models have a narrow dynamic range and are unfit to quantitative analysis because they use a TDC (Time-to-Digital Converter) as a data acquisition system. Their applications were mainly in qualitative analysis with exact mass measurement, and are limited in such fields as environmental studies and chemical dynamics that require only qualitative analysis. Because of detector saturation, these systems only show good mass acuracy when operated within a limited analyte concentration range.
• Evolved Gas Analysis of Iron Powder using a TG/DTA System with a High-resolution Multi-turn Mass Spectrometer

  Thermogravimetry/differential thermal analysis (TG/DTA) systems are often used to analyze the thermal behavior of metal materials. These systems measure changes in sample weight as they relate to programmed oven temperatures. It is generally known that during the measurement process, as the weight decreases, gases are evolved.