DEP is a technique in which a sample is applied directly to the platinum filament at the tip of the probe and the sample is rapidly heated by passing an electric current through the filament. This makes it possible to rapidly ionize the sample while minimizing thermal decomposition. Therefore, sample pretreatment is almost unnecessary, and it is suitable for the analysis of non-volatile substances or substances that are easily thermally decomposed. In this study, we attempted rapid qualitative analysis of the organic pigments contained in toner using DEP.